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Lithium-ion Battery Modelling Techniques

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Image source: A Comprehensive Review and Application of Metaheuristics in Solving the Optimal Parameter Identification Problems - Scientific Figure on ResearchGate. Available from: www.researchgate[dot]net/figure/Classification-of-lithium-ion-battery-models_fig4_369497317

To optimize the performance, safety, and lifespan of li-ion batteries, different battery modeling techniques are used. This summary offers a basic understanding for the sake of simplicity.


1) Electrochemical Models: 


Describe battery behavior by taking into account the chemical reactions occurring within the battery.


1.1) Single Particle Model (SPM): Simplifies a battery's complexity by presuming that all active particles in electrode have identical SoC. Offers valuable insights into the intercalation process.


1.2) Pseudo Two-Dimensional Model (P2DM): Provides detailed understanding by accounting for spatial distribution of variables like concentration & potential. Its detailed nature makes it computationally intensive.



2) Equivalent Circuit Models: 


Represent the battery using familiar electrical components, making them easy to comprehend & implement.


2.1) Rint Model: A straightforward equivalent circuit involving an open-circuit voltage source & internal resistance, can accurately predict battery performance under steady-state conditions.


2.2) Thevenin Model: Uses resistors & capacitors to represent battery polarization phenomena. It is widely used to estimate SoC & predict dynamic behaviors.


2.3) Generic Non-Linear (GNL) Model: Captures complex battery behaviors such as capacity fading by including non-linear elements. It requires more computational resources and detailed data.



3) Empirical Models: 


Derived from experimental observations & describe battery's behavior mathematically.


3.1) Shepherd Model: A simplistic model, represents discharge behavior of a battery. However, it often fails to account for factors like temperature effects and aging.


3.2) Unnewehr Universal Model: Comprehensive model accounting for a broader range of battery behaviors. Its complexity may limit its use in systems with computational constraints.


3.3) Nernst Model: Based on the Nernst equation & accounts for concentration of lithium ions, offering precise SoC estimation. Its inherent non-linearity, however, can make it computationally intensive.



4) Data-Driven Models: 


Utilize ML algorithms to predict the system's behavior.


4.1) Radial Basis Function Neural Network (RBFNN): Excellent at handling non-linear multi-dimensional function approximations & predicting SoC, SoH & RUL.


4.2) Support Vector Machine (SVM): SVMs have proven robust in estimating SoH and SoH of li-ion batteries, even under varying working conditions.


4.3) Extreme Learning Machine (ELM): ELM's speed & scalability make it advantageous in real-time battery management systems.

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